Functional Additives

7 Factors to Consider when Choosing Thermoplastic Microspheres or Rigid Microspheres

Posted by Mark Elve on Jun 8, 2023 1:10:26 PM
Mark Elve
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Thermoplastic microspheres and rigid microspheres serve different purposes based on their inherent properties. Thermoplastic microspheres are made from polymers that can be melted and re-solidified multiple times without significant degradation. Rigid microspheres, on the other hand, are composed of inflexible materials (like glass) that do not undergo significant changes in their physical state when subjected to temperature fluctuations.

 

Thermoplastic Microspheres vs Rigid Microspheres

Material composition is just the tip of the iceberg when comparing these two microsphere designs. Let's review some significant factors that may influence your decision in choosing thermoplastic microspheres or rigid microspheres: 

 

1) Microsphere Flexibility

Thermoplastic microspheres offer flexibility in terms of their processability and deformability. They can be easily melted, molded, or processed using heat-based techniques. This flexibility allows for customization and incorporation into various matrices or applications. In contrast, rigid microspheres typically maintain their shape and structure without undergoing significant deformation or processing. 

 

2) Microsphere Density

Thermoplastic microspheres often have lower density compared to rigid microspheres. This low density is desirable in applications where weight reduction is a priority, such as in lightweight composites or materials, adhesives, coatings, clays and materials requiring buoyancy. 

 

3) Mechanical Characteristics of Microspheres

Rigid microspheres tend to have higher mechanical strength and rigidity compared to thermoplastic microspheres. This property makes rigid microspheres suitable for applications that require enhanced structural integrity, impact resistance, or dimensional stability. 

 

4) Chemical Compatibility of Microspheres

Thermoplastic microspheres offer a wide range of chemical compatibility due to the choice of polymers available. They can be formulated to be compatible with various solvents, matrices, or environments. Rigid microspheres may have limitations in terms of chemical compatibility, and certain polymers may exhibit limited resistance to certain solvents or chemicals. 

Related Article: Pumping vs Dumping Microspheres: Choosing an Application Method

 

5) Thermal Stability

Thermoplastic microspheres are designed to have good thermal stability within their operating temperature range, allowing them to withstand processing temperatures without significant degradation. Rigid microspheres, depending on the material, may have higher thermal stability and can withstand higher temperatures without deformation. 

 

6) Surface Modification

Thermoplastic microspheres often have the advantage of surface modification or functionalization due to the nature of the thermoplastic polymers used. Surface modifications can enable improved compatibility, adhesion, dispersibility, or specific functionalities. Rigid microspheres may have limited options for surface modification depending on the material. 

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7) Expansion Potential for Microspheres

Thermoplastic microspheres, such as expandable microspheres, have the unique ability to expand in size when exposed to heat. This expansion capability is not typically observed in rigid microspheres and can be advantageous in applications that require foam formation, texture development, or insulation properties. For more information, check out our article on microspheres in the construction industry.

 

Final Thoughts

Ultimately, the choice between thermoplastic microspheres and rigid microspheres depends on the specific requirements of the application, including mechanical properties, processing conditions, chemical compatibility, and desired functionalities. Each type has its own advantages and considerations, and the selection should be based on the specific needs and performance criteria of the intended application. 

 If you need help coming to a decision, leave us a comment or reach out. Our specialists are more than happy to assist in answering any questions you may have on microspheres.

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Topics: Thermoplastic, Expanded Microspheres